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71.
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73.
Following the Aznalcóllar pyrite mine disaster (Seville, Spain) which caused the spilling of some 4.5?hm3 of acid water, the floodplains of the rivers Agrio and Guadiamar were rapidly cleaned of waste sludge. However, despite the efficiency of cleaning activities, there is still evidence of a fine superficial layer of sludge and some soil contamination, with the consequent risk of remobilisation of the pollutants by water erosion. There is much concern that these contaminated sediments may affect the precious ecosystems of the Doñana National Park and the Guadalquivir marshlands. This report describes the evaluation of the risk of mobilisation of the waste sludge through (1) detailed geomorphological analysis, indicating potential areas of erosion-sedimentation on the floodplains of the rivers Agrio and Guadiamar, and predicted dynamics of the waste sludge, and (2) evaluation of the potential dispersion of the waste sludge provoked by future flood events, including hydraulic calculations to model channel flow and the analysis of the texture of the sludge to obtain critical transport and sedimentation values. Findings suggest that the waste sludge is likely to be transported and deposited within the Doñana National Park during future flood events.  相似文献   
74.
For the period from 1958 to 1996, streamflow characteristics of a highly urbanized watershed were compared with less‐urbanized and non‐urbanized watersheds within a 20 000 km2 region in the vicinity of Atlanta, Georgia: in the Piedmont and Blue Ridge physiographic provinces of the southeastern USA. Water levels in several wells completed in surficial and crystalline‐rock aquifers were also evaluated. Data were analysed for seven US Geological Survey (USGS) stream gauges, 17 National Weather Service rain gauges, and five USGS monitoring wells. Annual runoff coefficients (RCs; runoff as a fractional percentage of precipitation) for the urban stream (Peachtree Creek) were not significantly greater than for the less‐urbanized watersheds. The RCs for some streams were similar to others and the similar streams were grouped according to location. The RCs decreased from the higher elevation and higher relief watersheds to the lower elevation and lower relief watersheds: values were 0·54 for the two Blue Ridge streams, 0·37 for the four middle Piedmont streams (near Atlanta), and 0·28 for a southern Piedmont stream. For the 25 largest stormflows, the peak flows for Peachtree Creek were 30% to 100% greater than peak flows for the other streams. The storm recession period for the urban stream was 1–2 days less than that for the other streams and the recession was characterized by a 2‐day storm recession constant that was, on average, 40 to 100% greater, i.e. streamflow decreased more rapidly than for the other streams. Baseflow recession constants ranged from 35 to 40% lower for Peachtree Creek than for the other streams; this is attributed to lower evapotranspiration losses, which result in a smaller change in groundwater storage than in the less‐urbanized watersheds. Low flow of Peachtree Creek ranged from 25 to 35% less than the other streams, possibly the result of decreased infiltration caused by the more efficient routing of stormwater and the paving of groundwater recharge areas. The timing of daily or monthly groundwater‐level fluctuations was similar annually in each well, reflecting the seasonal recharge. Although water‐level monitoring only began in the 1980s for the two urban wells, water levels displayed a notable decline compared with non‐urban wells since then; this is attributed to decreased groundwater recharge in the urban watersheds due to increased imperviousness and related rapid storm runoff. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
75.
Summary A case study and statistical evaluations provide evidence that so-called ozone mini-hole events over Europe, where a rapid drop of total ozone is followed by complete recovery after a few days, are due to the northeascward motion of patches of air with low total ozone content. These patches appear to originate in subtropical latitudes. They correlate well with minima of potential vorticity near the tropopause. Contour dynamics is invoked to explain some basic features of the deformation and northward motion of the mini-holes as well as the related large-scale flow structures.  相似文献   
76.
The curve of the reaction: 1 Rhodochrosite + 1 Quartz Pyroxmangite was determined experimentally using gas mixtures with different CO2H2O ratios at a total pressure of 2 kb. In pure CO2, the equilibrium temperature is 508±2° C. By plotting the equilibrium data in terms of InXCO2 versus reciprocal temperature, a H of reaction of 51.7 kcal was obtained. This plot shows a straight-line relationship, indicating internal consistency of the data, and is in good agreement with previous findings that CO2 and H2O mix ideally within the investigated temperature range (400–600° C). When applied to pyroxmangites formed during moderate greenschist facies metamorphism, these data indicate a high acitivity of H2O.  相似文献   
77.
K–Ar ages have been determined on micas and hornblendes in the basal metamorphic sequence and in metamorphic rocks squeezed into the mantle sequence of the Semail Ophiolite. The hornblende ages of 99±0.5 and 102±0.8 Ma and the 90 Ma ages of coexisting micas from the high-grade metamorphic portion of the sequence are interpreted as cooling stages following the peak of metamorphism (T 800–850° C, P 6.5–9 kbar). The new pressure estimates are based on findings of kyanite in garnet-amphibolite and cordierite in quartzitic rocks. These data indicate a cooling rate of 10–30° C/Ma. The oldest mica ages of 95±1 Ma are observed in the lowest-grade greenschists. These also largely represent cooling ages, but might in part also include formation ages. The pattern of the muscovite ages across the metamorphic sole indicates that the cooling front moved from the low-grade metamorphic zone, through the high-grade rocks and into the base of the overlying ophiolite. Radiometric ages of hornblendes (92.3±0.5 and 94.8±0.6 Ma) indicate that the crustal gabbro sequence cooled below 500° C later than the base of the ophiolite sequence. Metamorphism of the sole rocks occurred during subduction of oceanic sediments and volcanic or gabbroic rocks as they progressively came into contact with hotter zones at the base of the overriding plate. The peak of metamorphism must have been contemporaneous with the main magmatism in the Semail Ophiolite. One of the dated muscovites yields an age of 81.3±0.8 Ma, but this is related to discrete deformation zones that were active during late-stage emplacement of the ophiolite.  相似文献   
78.
A special shock tube process combining a reflected expansion wave with a weak shock wave is analyzed and calibrated. The process is employed to transfer water vapor carried in argon into a known supersaturated state for a short period of time (0.5 ms). During that period steady state homogeneous nucleation takes place followed by condensational growth. Nucleation and growth rates are measured by a 90° Mie-light scattering technique in the temperature range 200–260 K. The results are compared with existing theoretical models.  相似文献   
79.
Colonies of the shallow-water Caribbean coral Manicina areolata incorporated petroleum hydrocarbons into their tissues during exposure to water accommodated fractions of No. 2 fuel oil for three months. This contamination was not removed after depuration periods of up to two weeks. Although these corals remained alive, evidence of pathological responses was found which included impaired development of reproductive tissues, degeneration and loss of symbiotic zooxanthellae, and atrophy of mucous secretory cells and muscle bundles.  相似文献   
80.
The compositions of coexisting pyroxmangites, rhodonites, rhodochrosites and manganese calcites in regional metamorphosed manganese cale-silicate marbles from Val Scerscen and Alagna were analysed by microprobe and permit definition of critical tie lines at metamorphic grades appropriate to temperatures between 400 and 450 °C.Variations in composition of coexisting mineral pairs in one and the same locality are attributed to variations in and not to metamorphic temperatures. From the analysed assemblages isothermal plots (with SiO2 as excess component) were constructed for the system CaO-MnO-SiO2-CO2.  相似文献   
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